High Activity of Ce1-xNixO2-y for H2 Production through Ethanol Steam Reforming: Tuning Catalytic Performance through Metal-Oxide Interactions
Journal Article
·
· Angewandte Chemie International Edition
OSTI ID:1041779
The importance of the oxide: Ce{sub 0.8}Ni{sub 0.2}O{sub 2-y} is an excellent catalyst for ethanol steam reforming. Metal-oxide interactions perturb the electronic properties of the small particles of metallic nickel present in the catalyst under the reaction conditions and thus suppress any methanation activity. The nickel embedded in ceria induces the formation of O vacancies, which facilitate cleavage of the OH bonds in ethanol and water.
- Research Organization:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Organization:
- USDOE SC OFFICE OF SCIENCE (SC)
- DOE Contract Number:
- DE-AC02-98CH10886
- OSTI ID:
- 1041779
- Report Number(s):
- BNL-97457-2012-JA; TRN: US201212%%191
- Journal Information:
- Angewandte Chemie International Edition, Vol. 49, Issue 50
- Country of Publication:
- United States
- Language:
- English
Similar Records
High Activity of Ce1-xNixO2-y for H2 Production through Ethanol Steam Reforming: Tuning Catalytic Performance through Metal↔Oxide Interactions
Unusual Physical and Chemical Properties of Ni in Ce1-xNixO2-y Oxides: Structural Characterization and Catalytic Activity for the Water Gas Shift Reaction
Unusual Physical and Chemical Properties of Ni in Ce1-xNixO2-y Oxides: Structural Characterization and Catalytic Activity for the Water Gas Shift Reaction
Journal Article
·
Fri Dec 10 00:00:00 EST 2010
· Angewandte Chemie - International Edition
·
OSTI ID:1041779
+8 more
Unusual Physical and Chemical Properties of Ni in Ce1-xNixO2-y Oxides: Structural Characterization and Catalytic Activity for the Water Gas Shift Reaction
Journal Article
·
Thu Jul 29 00:00:00 EDT 2010
· Journal of Physical Chemistry C
·
OSTI ID:1041779
+5 more
Unusual Physical and Chemical Properties of Ni in Ce1-xNixO2-y Oxides: Structural Characterization and Catalytic Activity for the Water Gas Shift Reaction
Journal Article
·
Fri Jan 01 00:00:00 EST 2010
· Journal of Physical Chemistry C
·
OSTI ID:1041779
+5 more