Dynamic recovery in silicate-apatite structures under irradiation and implications for long-term immobilization of actinides

Journal Article · Sun Jan 01 00:00:00 EST 2012 · RSC Advances

DOI:https://doi.org/10.1039/c1ra00870f· OSTI ID:1032816

Weber, William J ^[1]; Zhang, Yanwen ^[1]; Xiao, Haiyan ^[2]; Wang, Prof. Lumin ^[3]

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1. ORNL
2. University of Tennessee, Knoxville (UTK)
3. University of Michigan

The irradiation responses of Ca2La8(SiO4)6O2 and Sr2Nd8(SiO4)6O2 with the apatite structure are investigated to predict their long-term behaviour as host phases for immobilization of actinide elements from the nuclear fuel cycle. Different ions and energies are used to study the effects of dose, temperature, atomic displacement rate and ionization rate on irradiation-induced amorphization and recrystallization. The dose for amorphization increases with temperature in two stages, below and above 150 K. In the high temperature stage relevant to actinide immobilization, the increase of amorphization dose with temperature exhibits a strong dependence on the ratio of ionization rate to displacement rate for the different ions. Data analysis using a dynamic model for amorphization reveals that ionization-induced processes, with activation energy of 0.15 0.02 eV, dominate dynamic recovery for ions from Ne through Xe. For heavier Au ions or for alpha-recoil nuclei emitted in alpha decay of actinides, ionization becomes less dominant and dynamic recovery is controlled primarily by thermally-driven processes. In post-irradiation annealing studies of amorphous samples, epitaxial thermal recrystallization is observed at 1123 K, and irradiation-enhanced nucleation of nanocrystallites is observed under irradiation with heavier ions. The recrystallization temperature under irradiation decreases with increasing ion mass to a value of ~ 823 K, which also defines the thermally-driven critical temperature for amorphization under irradiation with heavy ions. Some partial recovery due to alpha particle irradiation at 300 K is observed that suggests a self-healing mechanism in apatite phases containing actinides. Based on the results and dynamic model, the temperature and time dependences of amorphization in silicate-apatite host phases for actinide immobilization are predicted.

• Research Organization: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
• Sponsoring Organization: USDOE Office of Science (SC)
• DOE Contract Number: DE-AC05-00OR22725
• OSTI ID: 1032816
• Journal Information: RSC Advances, Vol. 2, Issue 2; ISSN 2046-2069
• Country of Publication: United States
• Language: English

Related Subjects

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS
ACTINIDES
ACTIVATION ENERGY
ALPHA DECAY
ALPHA PARTICLES
ANNEALING
APATITES
ATOMIC DISPLACEMENTS
CRITICAL TEMPERATURE
DATA ANALYSIS
HEAVY IONS
IONIZATION
IRRADIATION
NUCLEAR FUELS
NUCLEATION
NUCLEI
RECRYSTALLIZATION
TIME DEPENDENCE
Irradiation effects
apatite
actinides