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Title: Life-cycle CO{sub 2} emissions for air-blown gasification combined-cycle using selexol

Conference ·
OSTI ID:10177302

Initiatives to limit carbon dioxide (CO{sub 2}) emissions have drawn considerable interest to integrated gasification combined-cycle (IGCC) power generation. With its higher efficiency, this process can reduce CO{sub 2} production. It is also amenable to CO{sub 2} capture, because CO{sub 2} Can be removed before combustion and the associated dilution with atmospheric nitrogen. This paper presents a process-design baseline that encompasses the IGCC system, CO{sub 2} transport -by pipeline, and land-based sequestering of CO{sub 2} in geological reservoirs. The intent of this study is to provide the CO{sub 2} budget, or an ``equivalent CO{sub 2}`` budget, associated with each of the individual energy-cycle steps. Design capital and operating costs for the process are included in the fill study but are not reported in the present paper. The value used for the equivalent CO{sub 2} budget will be 1 kg CO{sub 2}/kWh{sub e}. The base case is a 470-MW (at the busbar) IGCC system using an air-blown Kellogg Rust Westinghouse (KRW) agglomerating fluidized-bed gasifier, US Illinois {number_sign}6 bituminous coal feed, and in-bed sulfur removal. Mining, feed preparation, and conversion result in a net electric power production of 461 MW, with a CO{sub 2} release rate of 0.830 kg/kWh{sub e}. In the CO{sub 2} recovery case, the gasifier output is taken through water-gas shift and then to Selexol, a glycol-based absorber-stripper process that recovers CO{sub 2} before it enters the combustion turbine. This process results in 350 MW at the busbar.

Research Organization:
Argonne National Lab., IL (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
W-31109-ENG-38
OSTI ID:
10177302
Report Number(s):
ANL/ES/CP-80375; CONF-9308137-1; ON: DE93018623
Resource Relation:
Conference: 1993 summer national American Institute of Chemical Engineers (AIChE) conference,Seattle, WA (United States),15-18 Aug 1993; Other Information: PBD: Jun 1993
Country of Publication:
United States
Language:
English