Treatment of high-level wastes from the IFR fuel cycle
The Integral Fast Reactor (IFR) is being developed as a future commercial power source that promises to have important advantages over present reactors, including improved resource conservation and waste management. The spent metal alloy fuels from an IFR will be processed in an electrochemical cell operating at 500{degree}C with a molten chloride salt electrolyte and cadmium metal anode. After the actinides have been recovered from several batches of core and blanket fuels, the salt cadmium in this electrorefiner will be treated to separate fission products from residual transuranic elements. This treatment produces a waste salt that contains the alkali metal, alkaline earth, and halide fission products; some of the rare earths; and less than 100 nCi/g of alpha activity. The treated metal wastes contain the rest of the fission products (except T, Kr, and Xe) small amounts of uranium, and only trace amounts of transuranic elements. The current concept for the salt waste form is an aluminosilicate matrix, and the concept for the metal waste form is a corrosion-resistant metal alloy. The processes and equipment being developed to treat and immobilize the salt and metal wastes are described.
- Research Organization:
- Argonne National Lab., IL (United States)
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- W-31109-ENG-38
- OSTI ID:
- 10160847
- Report Number(s):
- ANL/CP-75624; CONF-920815-3; ON: DE92017069
- Resource Relation:
- Conference: 204. American Chemical Society (ACS) national meeting,Washington, DC (United States),23-28 Aug 1992; Other Information: PBD: [1992]
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS
IFR REACTOR
FUEL CYCLE
SPENT FUELS
REPROCESSING
HIGH-LEVEL RADIOACTIVE WASTES
RADIOACTIVE WASTE PROCESSING
ELECTROCHEMICAL CELLS
ELECTROREFINING
FISSION PRODUCTS
SALTS
SOLIDIFICATION
WASTE FORMS
052001
210500
050800
210802
WASTE PROCESSING
POWER REACTORS
BREEDING
SPENT FUELS REPROCESSING