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Title: The relationship between glass viscosity and composition: A first principles model for vitrification of nuclear waste

Conference ·
OSTI ID:10130190

The Defense Waste Processing Facility will incorporate high-level liquid waste into borosilicate glass for stabilization and permanent disposal in a geologic repository. The viscosity of the melt determines the rate of melting of the raw feed, the rate of gas bubble release due to foaming and fining, the rate of homogenization, and thus, the quality of the glass produced. The viscosity of the glass is in turn, a function of both glass composition and temperature. A model describing the viscosity dependence on composition, temperature, and glass structure (bonding) has been derived for glasses ranging from pure frits to frit plus 35 wt % simulated waste. 17 refs., 37 figs.

Research Organization:
Westinghouse Savannah River Co., Aiken, SC (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC09-89SR18035
OSTI ID:
10130190
Report Number(s):
WSRC-MS-90-41; CONF-900407-9; ON: DE92009658
Resource Relation:
Conference: 92. annual meeting of the American Ceramic Society,Dallas, TX (United States),22-26 Apr 1990; Other Information: PBD: [1990]
Country of Publication:
United States
Language:
English