Molecular and polymeric ceramic precursors. Research progress report, December 1, 1990--November 30, 1991
The development of new methods for the production of complex materials is one of the most important problems in modern solid state chemistry and materials science. This project is attempting to apply the synthetic principles which have evolved inorganic and organometallic chemistry to the production of technologically important non-oxide ceramics, such as boron nitride, boron carbide and metal borides. Our recent work has now resulted in the production of new polymer systems, including poly(B-vinylborazine), polyvinylpentaborane and polyborazylene, that have proven to be high yield precursors to boron-based ceramic materials. Current work is now directed toward the synthesis of new types of molecular and polymeric boron-containing species and on exploration of the solid state properties of the ceramics that have been produced in these studies.
- Research Organization:
- Pennsylvania Univ., Philadelphia, PA (United States). Board of Trustees
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- FG02-87ER13732
- OSTI ID:
- 10103417
- Report Number(s):
- DOE/ER/13732-4; ON: DE92003694
- Resource Relation:
- Other Information: PBD: Aug 1991
- Country of Publication:
- United States
- Language:
- English
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Molecular and polymeric ceramic precursors
Molecular and polymeric ceramic precursors. Research progress report
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ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE
BORON NITRIDES
CHEMICAL PREPARATION
BORON CARBIDES
INORGANIC POLYMERS
PROGRESS REPORT
BORIDES
BORON COMPOUNDS
CHEMICAL REACTION YIELD
CHEMICAL PROPERTIES
400201
360601
CHEMICAL AND PHYSICOCHEMICAL PROPERTIES
PREPARATION AND MANUFACTURE